Locally controlled MOF growth on functionalized carbon nanotubes

authored by: Marvin J. Dzinnik, Necmettin E. Akmaz, Adrian Hannebauer, Andreas Schaate, Peter Behrens, Rolf J. Haug
Abstract: Metal-organic frameworks (MOFs) are highly versatile materials because of their tunable properties. However, the typically poor electrical conductivity of MOFs presents challenges for their integration into electrical devices. By adding carbon nanotubes to MOF synthesis, a highly intergrown material with increased conductivity and chemiresistive sensing properties can be obtained. Here, we present a patterning technique to control MOF growth on predefined areas of one particular carbon nanotube. We found that electron beam pretreatment of -COOH functionalized multi-walled carbon nanotubes inhibits the growth of UiO-66 MOF on these multi-walled carbon nanotubes. By irradiating individual multi-walled carbon nanotubes, we show that MOF growth can be inhibited in predefined tube areas, creating MOF-free spaces on the nanotube. In this way, our method shows a possibility to pattern MOF growth on individual nanotubes.
Organisation(s): Institute of Solid State Physics
Institute of Inorganic Chemistry
Laboratory of Nano and Quantum Engineering
QuantumFrontiers
PhoenixD: Photonics, Optics, and Engineering - Innovation Across Disciplines
Type: Article
Journal: Communications Materials
Volume: 5
No. of pages: 7
Publication date: 16.03.2024
Publication status: Published
Peer reviewed: Yes
ASJC Scopus subject areas: Materials Science(all), Mechanics of Materials
Electronic version(s): https://doi.org/10.1038/s43246-024-00473-9 (Access: Open)

BibTeX

@article{6b313219698249b691fbdf23293fd4a5,
title = "Locally controlled MOF growth on functionalized carbon nanotubes",
abstract = "Metal-organic frameworks (MOFs) are highly versatile materials because of their tunable properties. However, the typically poor electrical conductivity of MOFs presents challenges for their integration into electrical devices. By adding carbon nanotubes to MOF synthesis, a highly intergrown material with increased conductivity and chemiresistive sensing properties can be obtained. Here, we present a patterning technique to control MOF growth on predefined areas of one particular carbon nanotube. We found that electron beam pretreatment of -COOH functionalized multi-walled carbon nanotubes inhibits the growth of UiO-66 MOF on these multi-walled carbon nanotubes. By irradiating individual multi-walled carbon nanotubes, we show that MOF growth can be inhibited in predefined tube areas, creating MOF-free spaces on the nanotube. In this way, our method shows a possibility to pattern MOF growth on individual nanotubes.",
author = "Dzinnik, {Marvin J.} and Akmaz, {Necmettin E.} and Adrian Hannebauer and Andreas Schaate and Peter Behrens and Haug, {Rolf J.}",
note = "Funding Information: This work was funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany{\textquoteright}s Excellence Strategy-EXC 2123 Quantum Frontiers-390837967 and EXC 2122 PhoenixD-390833453. A.H. is grateful for being funded by the Hannover School for Nanotechnology (HSN) at the Laboratory of Nano and Quantum Engineering (LNQE). The HSN is funded by the Ministry of Science and Culture of Lower Saxony.",
year = "2024",
month = mar,
day = "16",
doi = "10.1038/s43246-024-00473-9",
language = "English",
volume = "5",
journal = "Communications Materials",
issn = "2662-4443",
publisher = "Springer Nature",
}