Synthesis of a Recoverable CuS/Fe₃O₄ Composite Structure with Enhanced Oxidase-Like Activity for Detection of Chromium (VI)

verfasst von

Kuda Feke, Melisew Tadele Alula, Hendrik Spende, Andreas Waag, Peter Lemmens

Abstract

In this study, CuS/Fe₃O₄ composite structures were prepared in a two-step process. Initially, we used a simple solvothermal method to synthesize CuS nanostructures. Hydrothermal method was employed to form CuS/Fe₃O₄ composites. We characterized the particles using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The particles exhibit an oxidase-like activity using the colorless 3,3′,5,5′-tetramethylbenzidine (TMB) as oxidase substrate. The presence of chromium (VI) increases the oxidase-like activity and is dependent on the concentration. The UV/visible absorption intensity of the oxidized TMB (oxTMB) increases with the concentration of chromium (VI) which provides a route to colorimetric determination of chromium (VI). We noticed a limit of detection as small as 60 nM and a wide linear dynamic range of 0–1500 µM. We found a high selectivity of this method for chromium (VI) against potentially interference cations and anions. Its applicability for determination of chromium (VI) in real environmental samples is demonstrated using tap water. This result demonstrates the capability of the method in determination of chromium (VI) in real samples.

Externe Organisation(en)

Botswana International University of Science and Technology
Technische Universität Braunschweig

Typ

Artikel

Journal

Journal of cluster science

Band

34

Seiten

1009-1018

Anzahl der Seiten

10

ISSN

1040-7278

Publikationsdatum

03.2023

Publikationsstatus

Veröffentlicht

Peer-reviewed

Ja

ASJC Scopus Sachgebiete

Biochemie, Chemie (insg.), Werkstoffwissenschaften (insg.), Physik der kondensierten Materie

Elektronische Version(en)

https://doi.org/10.1007/s10876-022-02284-9 (Zugang: Geschlossen)