Monitoring the Morphological Changes of Skeleton-PtCo Electrocatalyst during PEMFC Start-Up/Shut-Downprobed by in situ WAXS and SAXS

verfasst von: Marek Janssen, Jakub Drnec, Isaac Martens, Jonathan Quinson, Rebecca Pittkowski, Daesung Park, Philipp Weber, Matthias Arenz, Mehtap Oezaslan
Abstract: Advanced in situ analyses are indispensable for comprehending the catalyst aging mechanisms of Pt-based PEM fuel cell cathode materials, particularly during accelerated stress tests (ASTs). In this study, a combination of in situ small-angle and wide-angle X-ray scattering (SAXS & WAXS) techniques were employed to establish correlations between structural parameters (crystal phase, quantity, and size) of a highly active skeleton-PtCo (sk-PtCo) catalyst and their degradation cycles within the potential range of the start-up/shut-down (SUSD) conditions. Despite the complex case of the sk-PtCo catalyst comprising two distinct fcc alloy phases, our complementary techniques enabled in situ monitoring of structural changes in each crystal phase in detail. Remarkably, the in situ WAXS measurements uncover two primary catalyst aging processes, namely the cobalt depletion (regime I) followed by the crystallite growth via Ostwald ripening and/or particle coalescence (regime II). Additionally, in situ SAXS data reveal a continuous size growth over the AST. The Pt-enriched shell thickening based on the Co depletion within the first 100 SUSD cycles and particle growth induced by additional potential cycles were also collaborated by ex situ STEM-EELS. Overall, our work shows a comprehensive aging model for the sk-PtCo catalyst probed by complementary in situ WAXS and SAXS techniques.
Externe Organisation(en): Technische Universität Braunschweig
European Synchrotron Radiation Facility
Aarhus University
Københavns Universitet
Physikalisch-Technische Bundesanstalt (PTB)
University of Bern
Typ: Artikel
Journal: CHEMSUSCHEM
Band: 17
ISSN: 1864-5631
Publikationsdatum: 09.09.2024
Publikationsstatus: Veröffentlicht
Peer-reviewed: Ja
ASJC Scopus Sachgebiete: Umweltchemie, Chemische Verfahrenstechnik (insg.), Werkstoffwissenschaften (insg.), Energie (insg.)
Elektronische Version(en): https://doi.org/10.1002/cssc.202400303 (Zugang: Offen)

BibTeX

@article{3c3ebb679a384841a730343a4ea6bbd0,
title = "Monitoring the Morphological Changes of Skeleton-PtCo Electrocatalyst during PEMFC Start-Up/Shut-Downprobed by in situ WAXS and SAXS",
abstract = "Advanced in situ analyses are indispensable for comprehending the catalyst aging mechanisms of Pt-based PEM fuel cell cathode materials, particularly during accelerated stress tests (ASTs). In this study, a combination of in situ small-angle and wide-angle X-ray scattering (SAXS & WAXS) techniques were employed to establish correlations between structural parameters (crystal phase, quantity, and size) of a highly active skeleton-PtCo (sk-PtCo) catalyst and their degradation cycles within the potential range of the start-up/shut-down (SUSD) conditions. Despite the complex case of the sk-PtCo catalyst comprising two distinct fcc alloy phases, our complementary techniques enabled in situ monitoring of structural changes in each crystal phase in detail. Remarkably, the in situ WAXS measurements uncover two primary catalyst aging processes, namely the cobalt depletion (regime I) followed by the crystallite growth via Ostwald ripening and/or particle coalescence (regime II). Additionally, in situ SAXS data reveal a continuous size growth over the AST. The Pt-enriched shell thickening based on the Co depletion within the first 100 SUSD cycles and particle growth induced by additional potential cycles were also collaborated by ex situ STEM-EELS. Overall, our work shows a comprehensive aging model for the sk-PtCo catalyst probed by complementary in situ WAXS and SAXS techniques.",
keywords = "accelerated stress test (AST), oxygen reduction reaction (ORR), skeleton-PtCo nanoparticles (NPs), small-angle X-ray scattering (SAXS), start-up/shut-down (SUSD), wide-angle X-ray scattering (WAXS)",
author = "Marek Janssen and Jakub Drnec and Isaac Martens and Jonathan Quinson and Rebecca Pittkowski and Daesung Park and Philipp Weber and Matthias Arenz and Mehtap Oezaslan",
note = "Publisher Copyright: {\textcopyright} 2024 The Authors. ChemSusChem published by Wiley-VCH GmbH.",
year = "2024",
month = sep,
day = "9",
doi = "10.1002/cssc.202400303",
language = "English",
volume = "17",
journal = "CHEMSUSCHEM",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "17",
}